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Bamboo-like -doped carbon nanotubes encapsulating M(Co, Fe)-Ni alloy for electrochemical production of

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 4, Pages 498-510 doi: 10.1007/s11705-021-2082-6

Abstract: The electrochemical conversion of CO2sub>-H2sub>O into CO-H2sub> using renewableHerein, a series of N-doped carbon nanotubes encapsulating binary alloy nanoparticles (Msub>2sub> ratios of 2:1 and 1.5:1, corresponding to the ratio to producebiofuels by syngas fermentation, could be realized on Co1sub>Ni-NCNT and Co2sub>Ni-NCNT>2sub> ratio from electrochemical CO2sub> reduction.

Keywords： electrochemical reduction of CO2sub> syngas N-doped carbon nanotubes encapsulated alloynanoparticles CO/H2sub> ratio

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Theoretical and experimental study on the fluidity performance of hard-to-fluidize carbon nanotubes-basedCO2 capture sorbents

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 10, Pages 1460-1475 doi: 10.1007/s11705-022-2159-x

Abstract: Carbon nanotubes-based materials have been identified as promising sorbents for efficient CO2sub> capture in fluidized beds, suffering from insufficient contact with CO2sub> for the high-levelCO2sub> capture capacity.Pure carbon nanotubes + 7.5 wt% SiO2sub> and synthesized carbon nanotubes + 5 wt% SiO2subChemical modification of carbon nanotubes causes not only enhanced CO 2sub> uptake capacity but

Keywords： CO2sub> capture CNT-based sorbents fluidization SiO2sub> nanoparticles fluidized bed

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Efficient synthesis of titania nanotubes and enhanced photoresponse of Pt decorated TiO

Yuxin YIN, Xin TAN, Feng HOU, Lin ZHAO

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 3, Pages 298-304 doi: 10.1007/s11705-009-0019-6

Abstract: Furthermore, Pt nanoparticles were successfully deposited on the surface of TiO nanotubes by ac electrodepositionAn enhancement in photocurrent density has been achieved upon modification of TiO nanotubes with Pt

Keywords： TiO2sub> nanotube arrays HMT TiO2sub>/Pt Photocurrent density

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Enhanced activation of peroxymonosulfate by CNT-TiO

Xuemin Hao, Guanlong Wang, Shuo Chen, Hongtao Yu, Xie Quan

Frontiers of Environmental Science & Engineering 2019, Volume 13, Issue 5, doi: 10.1007/s11783-019-1161-0

Abstract: CNT-TiO2 composite is used to activate PMS under UV-light assistance.SO4•−, •OH and 1O2 play key roles in the degradation of organic pollutants.peroxymonosulfate (PMS) activation system was constructed with the composite catalyst of multi-walled carbon nanotubes(CNT) - titanium dioxide (TiO2).in the UV/PMS/20%CNT-TiO2 system.

Keywords： Peroxymonosulfate activation Carbon nanotubes TiO2sub> Water treatment

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Effect of metal ion-doping on characteristics and photocatalytic activity of TiO

Rongfang YUAN,Beihai ZHOU,Duo HUA,Chunhong SHI

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 5, Pages 850-860 doi: 10.1007/s11783-014-0737-y

Abstract: The effect of ion-doping on TiO nanotubes were investigated to obtain the optimal TiO nanotubes forthe catalysts on HA removal increased when Ag , Al , Cu , Fe , V , and Zn were doped into the TiO nanotubesIn the presence of 1.0 at.% Fe -doped TiO nanotubes calcined at 550°C, the removal efficiency of HA

Keywords： TiO2sub> nanotubes ion-doping humic acids pseudo-first-order mechanism

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Potassium and Manganese Promoters on Nitrogen-Doped Carbon Nanotube-Supported Iron Catalysts for CO2sub> Hydrogenation Article

Praewpilin Kangvansura, Ly May Chew, Chanapa Kongmark, Phatchada Santawaja, Holger Ruland, Wei Xia, Hans Schulz, Attera Worayingyong, Martin Muhler

Engineering 2017, Volume 3, Issue 3, Pages 385-392 doi: 10.1016/J.ENG.2017.03.013

Abstract:

Nitrogen-doped carbon nanotubes (NCNTs) were used as a support for iron (Fe) nanoparticles appliedin carbon dioxide (CO2sub>) hydrogenation at 633 K and 25 bar (1 bar = 10⁵ Pa).>2sub> hydrogenation, reaching 34.9% conversion with a gas hourly space velocity (GHSV) of 3.1 L·>2sub>), and in situ X-ray absorption near-edge structure (XANES) analysis.Catalytic ammonia (NH3sub>) decomposition was used as an additional probe reaction for characterizing

Keywords： CO2sub> hydrogenation Iron catalyst Nitrogen-doped carbon nanotubes Manganese promoter Potassium

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Solar photocatalytic decomposition of two azo dyes on multi-walled carbon nanotubes (MWCNTs)/TiO 2 composites

Huilong WANG, Shuqin LIU, Hui WANG, Wenfeng JIANG,

Frontiers of Environmental Science & Engineering 2010, Volume 4, Issue 3, Pages 311-320 doi: 10.1007/s11783-010-0237-7

Abstract: Multi-walled carbon nanotubes (MWCNTs)/TiO composite photocatalysts with high photoactivity were prepared

Keywords： sol-gel multi-walled carbon nanotubes (MWCNTs)/TiO2 composite photocatalysis azo dye solar irradiation

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Rh2sub>O3sub>/hexagonal CePO4sub> nanocatalysts for N2sub>O decomposition

Huan Liu, Zhen Ma

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 4, Pages 586-593 doi: 10.1007/s11705-017-1659-6

Abstract: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

Keywords： Rh2sub>O3sub> CePO4sub> N2sub>O decomposition

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CO2sub> methanation and co-methanation of CO and CO2sub> over Mn-promoted Ni/Al2sub>O3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2, Pages 273-280 doi: 10.1007/s11705-016-1563-5

Abstract: A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnation method. The effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanation of CO and CO in a fixed-bed reactor was investigated. The catalysts were characterized by N physisorption, hydrogen temperature-programmed reduction and desorption, carbon dioxide temperature-programmed desorption, X-ray diffraction and high-resolution transmission electron microscopy. The presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomeration due to improved Ni dispersion and weakened interactions between the nickel species and the support. The Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperatures (250 to 400 °C). The Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/Al O catalyst. The co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the CO methanation activity especially at low temperatures but it had little influence on the CO methanation performance. CO methanation was more sensitive to the reaction temperature and the space velocity than the CO methanation in the co-methanation process.

Keywords： Mn promotion nickel catalysts CO2sub> methanation co-methanation of CO and CO2sub>

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A Storage-Driven CO2sub> EOR for a Net-Zero Emission Target Article

Yueliang Liu, Zhenhua Rui

Engineering 2022, Volume 18, Issue 11, Pages 79-87 doi: 10.1016/j.eng.2022.02.010

Abstract: >2sub>) emissions.>2sub> emissions by storing CO2sub> in oil reservoirs.CO2sub> EOR—whose main target is to realize net-zero or even negative CO2sub> emissionsStorage-driven CO2sub> EOR is superior to conventional CO2sub> EOR in improving sweepingthan conventional CO2sub> EOR.

Keywords： CO2sub> EOR Net CO2sub> emissions Dimethyl ether Storage-driven CO2sub> EOR CO2sub> sequestration

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Al2sub>O3sub> and CeO2sub>-promoted MgO sorbents for CO2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1, Pages 83-93 doi: 10.1007/s11705-017-1691-6

Abstract: A series of Al O and CeO modified MgO sorbents was prepared and studied for CO sorption at moderate temperatures. The CO sorption capacity of MgO was enhanced with the addition of either Al O or CeO . Over Al O -MgO sorbents, the best capacity of 24.6 mg-CO /g-sorbent was attained at 100 °C, which was 61% higher than that of MgO (15.3 mg-CO /g-sorbent). The highest capacity of 35.3 mg-CO /g-sorbent was obtained over the CeO -MgO sorbents at the optimal temperature of 200 °C. Combining with the characterization results, we conclude that the promotion effect on CO sorption with the addition of Al O and CeO can be attributed to the increased surface area with reduced MgO crystallite size. Moreover, the addition of CeO increased the basicity of MgO phase, resulting in more increase in the CO capacity than Al O promoter. Both the Al O -MgO and CeO -MgO sorbents exhibited better cyclic stability than MgO over the course of fifteen CO sorption-desorption cycles. Compared to Al O , CeO is more effective for promoting the CO capacity of MgO. To enhance the CO capacity of MgO sorbent, increasing the basicity is more effective than the increase in the surface area.

Keywords： CO2sub> capture MgO sorbents Al2sub>O3sub> CeO2sub> flue gas

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The stabilization effect of Al2sub>O3sub> on unconventional Pb/SiO2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10, Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al2sub>O3sub> with a small amount, wasintroduced into Pb/SiO2sub> catalyst in this study.It has been proved that Al2sub>O3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO2sub> catalyst exhibits a much higher stability up to more than 150 h.>2sub>O3sub> addition was also proposed.

Keywords： Pb/SiO2sub> Al2sub>O3sub> propane dehydrogenation propene stability

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Cu-doped Bi/Bi2sub>WO6sub> catalysts for efficient N2sub> fixation by photocatalysis

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10, Pages 1412-1422 doi: 10.1007/s11705-023-2312-1

Abstract: it in photocatalytic N2sub> immobilization.>2sub>WO6sub> composite.>2sub>WO6sub>.>2sub>WO6sub>, respectively.>2sub>-to-NH3sub> conversion.

Keywords： Bi2sub>WO6sub> Cu doping work function photocatalytic N2sub> fixation charge

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Insights into the electron transfer mechanisms of permanganate activation by carbon nanotube membrane for enhanced micropollutants degradation

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 9, doi: 10.1007/s11783-023-1706-0

Abstract:

● A CNT filter enabled effective KMnO4sub> activation via

Keywords： KMnO4sub> Carbon nanotubes Non-radical pathway Electron transfer Water treatment

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ZnFe2sub>O4sub> deposited on BiOCl with exposed (001) and (010) facets for photocatalyticreduction of CO2sub> in cyclohexanol

Guixian Song, Xionggang Wu, Feng Xin, Xiaohong Yin

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 2, Pages 197-204 doi: 10.1007/s11705-016-1606-y

Abstract: ZnFe O -BiOCl composites were prepared by both hydrothermal and direct precipitation processes and the structures and properties of the samples were characterized by various instrumental techniques. The samples were then used as catalysts for the photocatalytic reduction of CO in cyclohexanol under ultraviolet irradiation to give cyclohexanone (CH) and cyclohexyl formate (CF). The photocatalytic CO reduction activities over the hydrothermally prepared ZnFe O -BiOCl composites were higher than those over the directly-precipitated composites. This is because compared to the direct-precipitation sample, the ZnFe O nanoparticles in the hydrothermal sample were smaller and more uniformly distributed on the surface of BiOCl and so more heterojunctions were formed. Higher CF and CH yields were obtained for the pure BiOCl and BiOCl composite samples with more exposed (001) facets than for the samples with more exposed (010) facets. This is due to the higher density of oxygen atoms in the exposed (001) facets, which creates more oxygen vacancies, and thereby improves the separation efficiency of the electron-hole pairs. More importantly, irradiation of the (001) facets with ultraviolet light produces photo-generated electrons which is helpful for the reduction of CO to ·CO . The mechanism for the photocatalytic reduction of CO in cyclohexanol over ZnFe O -BiOCl composites with exposed (001) facets involves electron transfer and carbon radical formation.

Keywords： reduction of CO2sub> cyclohexanol ZnFe2sub>O4sub> deposited BiOCl facet composite

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Title Author Date Type Operation

Bamboo-like -doped carbon nanotubes encapsulating M(Co, Fe)-Ni alloy for electrochemical production of

Journal Article

Theoretical and experimental study on the fluidity performance of hard-to-fluidize carbon nanotubes-basedCO2 capture sorbents

Journal Article

Efficient synthesis of titania nanotubes and enhanced photoresponse of Pt decorated TiO

Yuxin YIN, Xin TAN, Feng HOU, Lin ZHAO

Journal Article

Enhanced activation of peroxymonosulfate by CNT-TiO

Xuemin Hao, Guanlong Wang, Shuo Chen, Hongtao Yu, Xie Quan

Journal Article

Effect of metal ion-doping on characteristics and photocatalytic activity of TiO

Rongfang YUAN,Beihai ZHOU,Duo HUA,Chunhong SHI

Journal Article

Potassium and Manganese Promoters on Nitrogen-Doped Carbon Nanotube-Supported Iron Catalysts for CO2sub> Hydrogenation

Praewpilin Kangvansura, Ly May Chew, Chanapa Kongmark, Phatchada Santawaja, Holger Ruland, Wei Xia, Hans Schulz, Attera Worayingyong, Martin Muhler

Journal Article

Solar photocatalytic decomposition of two azo dyes on multi-walled carbon nanotubes (MWCNTs)/TiO 2 composites

Huilong WANG, Shuqin LIU, Hui WANG, Wenfeng JIANG,

Journal Article

Rh2sub>O3sub>/hexagonal CePO4sub> nanocatalysts for N2sub>O decomposition

Huan Liu, Zhen Ma

Journal Article

CO2sub> methanation and co-methanation of CO and CO2sub> over Mn-promoted Ni/Al2sub>O3sub> catalysts

Kechao Zhao,Zhenhua Li,Li Bian

Journal Article

A Storage-Driven CO2sub> EOR for a Net-Zero Emission Target

Yueliang Liu, Zhenhua Rui

Journal Article

Al2sub>O3sub> and CeO2sub>-promoted MgO sorbents for CO2sub> capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Journal Article

The stabilization effect of Al2sub>O3sub> on unconventional Pb/SiO2sub> catalyst

Journal Article

Cu-doped Bi/Bi2sub>WO6sub> catalysts for efficient N2sub> fixation by photocatalysis

Journal Article

Insights into the electron transfer mechanisms of permanganate activation by carbon nanotube membrane for enhanced micropollutants degradation

Journal Article

ZnFe2sub>O4sub> deposited on BiOCl with exposed (001) and (010) facets for photocatalyticreduction of CO2sub> in cyclohexanol

Guixian Song, Xionggang Wu, Feng Xin, Xiaohong Yin

Journal Article

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